Itaconic acid

Itaconic acid

Khoom Taw qhia

Itaconic acid Cov ntaub ntawv yooj yim
Khoom npe: Itaconic acid
Synonyms: methylene-butanedioicaci; methylene-succinicaci; Succinic acid, methylene-; 3-CARBOXY-3-BUTENOIC ACID; METHYLENESUCCINIC ACID; ITACONIC ACID; 2-TSHIAB-1, {{7} }DICARBOXYLIC ACID; PROPYLENEDICARBOXYLIC ACID
CAS: 97-65-4
MF: C5H6O4
MW: 130.1
EINECS: 202-599-6
Khoom Categories: Tsev Blocks; C1 txog C5; Carbonyl Compounds; Carboxylic Acids; Chemical Synthesis; Organic Building Blocks; Organic Chemicals; Pyridines; bc0001; 97-65-4
Mol File: 97-65-4.mol
Itaconic acid Structure
 
Itaconic acid Chemical Properties
Melting point 165-168 degree (lit.)
Boiling point 268 degree
ceev 1.573 g / mL ntawm 25 degree (lit.)
vapor siab 0.0000115 Pa (20 degree)
Refractive Index 1.4980 (kwv yees)
Fp 268 degree
cia temp. Khaws hauv qab +30 degree .
solubility 77.49g/l
daim ntawv Crystalline hmoov los yog Crystals
pka ua 3.85 (ntawm 25 degree)
Specific Gravity 1.573
xim Dawb rau lub teeb beige
PH 3.5 (1 mM tov); 2.95 (10 mM tov); 2.43 (100 mM tov);
tsw Yam ntxwv tsw
Dej Solubility Soluble hauv dej, acetone, methanol, hexane thiab ethanol. Me ntsis soluble hauv benzene, chloroform, carbon disulfide thiab roj av ether.
rhiab heev Hygroscopic
Merck 14,5242
BRN 1759501
Kev ruaj ntseg: Lub teeb Sensitive
InChIKey LVHBHZANLOWSRM-UHFFFAOYSA-N
LogP -0.301 ntawm 20 degree
CAS DataBase Reference 97-65-4(CAS DataBase Reference)
NIST Chemistry Reference Butanedioic acid, methylene-(97-65-4)
EPA Tshuaj Registry System Itaconic acid (97-65-4)
 
Cov ntaub ntawv kev nyab xeeb
Hazard Codes Xis
Risk Statements 36/37/38
Cov lus hais txog kev nyab xeeb 26-36
WGK Germany 1
Autoignition Kub 430 degree
TSCA Yog lawm
HS Code 29171990
Cov Ntaub Ntawv Muaj Xwm Ceev 97-65-4(Cov ntaub ntawv muaj phom sij)
Toxicity LD50 qhov ncauj hauv Luav:> 2000 mg / kg
 
MSDS Cov Ntaub Ntawv
Tus kws kho mob Lus
Methylenebutanedioic acid Lus Askiv
SigmaAldrich Lus Askiv
ACROS Lus Askiv
ALFA Lus Askiv
 
Itaconic acid Siv thiab Synthesis
Chemical Properties dawb mus rau lub teeb beige crystalline hmoov
Siv Copolymerizations, resins, plasticizers, lube-roj additive, nruab nrab.
Siv Kev siv loj rau itaconic acid yog nyob rau hauv copolymerizations, resins, plasticizers, thiab li roj additives.
Siv Itaconic acid yog siv rau hauv kev npaj ntawm acrylonitrile-butadiene-styrene thiab acrylate latexes. Nws kuj yog siv los npaj poly-itaconic acid, resins biofuel Cheebtsam thiab ionomer cements. Nws pom daim ntawv thov nyob rau hauv textile, tshuaj thiab tshuaj industries. Nws kuj yog siv los ua ib qho additive nyob rau hauv fibers thiab ion pauv resins kom abrasion, waterproofing, lub cev tsis kam, tuag affinity thiab zoo lub sij hawm. Tsis tas li ntawd, nws ua raws li ib tug co-monomer siv nyob rau hauv kev npaj ntawm acrylic fibers thiab rubbers, reinforced iav fiber, dag pob zeb diamond thiab lens. Nyob rau hauv tas li ntawd, nws ua raws li ib tug binder thiab sizing tus neeg saib xyuas nyob rau hauv tsis-woven fibers.
Txhais itaconic acid: Ib yam khoom ntawm fermentation ntawm flamentous fungusAspergillus niger. Itaconic acid yog siv los ua lag luam hauv kev tsim cov nplaum thiab xim.
Txhais ChEBI: Ib tug dicarboxylic acid uas yog methacrylic acid nyob rau hauv uas ib tug ntawm cov methyl hydrogens yog hloov los ntawm ib pawg carboxylic acid.
Kev piav qhia dav dav Itaconic acid, ib qho unsaturated dicarbonic organic acid, yog cov khoom lag luam metabolic ntawmAspergillus itaconicus yog qhov txawv txav.
Flammability thiab Explosibility Tsis yog nplaim taws
Txoj Kev Purification Crystallize itaconic acid los ntawm EtOH, EtOH / dej los yog EtOH / * benzene. [Beilstein 2 IV 2228.]
 
Itaconic acid Kev npaj cov khoom thiab cov ntaub ntawv raw
Cov khoom nyoos CIS-BUTENEDIOIC ANHYDRIDE-->Starch-->Succinic anhydride-->THORIUM-->Citraconic acid-->ACONITIC ACID, trans-(RG)-->ANTIOXIDANT 765
Cov khoom npaj 1-(2-AMINOETHYL)-4-BENZYLPIPERAZINE-->Dimethyl itaconate-->Itaconic anhydride-->3-Hydroxyglutaric Acid-->propene-->Methacrylic acid-->Dimethyl (R)-(+)-methylsuccinate-->ITACONIC ACID MONO-N-BUTYL ESTER-->(R)-(+)-Methylsuccinic acid-->3-METHYLTETRAHYDROFURAN-->Itaconic acid monomethyl ester

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