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O-Tolidine

O-Tolidine

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Khoom Taw qhia

O-Tolidine Cov ntaub ntawv yooj yim
Khoom npe: O-Tolidine
Synonyms: 3,3'-Dimethyl-[1,1'-biphenyl] -4,4'-Diamine (O-Tolidine); 1'-biphenyl) -4, 4'-diamine, 3,3 '-dimethyl-(;1'-Biphenyl)-4,4'-diamine,3,3'-dimethyl-(1;1'-biphenyl)-4,4'-diamine{{35 }},3'-dimethyl-(;1'-biphenyl]-4,4'-diamine,3,3'-dimethyl-[;2-Tolidin;2-Tolidina;{ {50}}Tolidine
CAS: 119-93-7
MF: C14H16N2
MW: 212.29
EINECS: 204-358-0
Khoom Categories: Organics; Intermediates ntawm Dyes thiab Pigments; tshuaj zoo, tshuaj tshwj xeeb, intermediates, hluav taws xob chemical, organic synthesis; Tsim Blocks; Chemical Synthesis; Nitrogen Compounds; Organic Building Blocks; Polyamines
Mol File: 119-93-7.mol
O-Tolidine Structure
 
O-Tolidine Chemical Properties
Melting point 128-131 degree (lit.)
Boiling point 300.5 degree
ceev 0.9678 (nqi kwv yees)
Refractive Index n20/D 1.341
Fp 244 degree
cia temp. -20 degree
solubility 2% HCl: 10 mg / ml, ntshiab
Xim Index 37230
daim ntawv hmoov (tej zaum yuav muaj pob)
pka ua 4.59 ± 0.10 (Tshaj tawm)
xim lub teeb xim av
Dej Solubility Me ntsis soluble hauv dej.
Merck 14,9514
BRN 2210640
Kev txwv tsis pub dhau TLV-TWA none; carcinogenicity: A2 - Suspected Human Carcinogen (ACGIH), Tsiaj Ntawv Pov Thawj (IARC).
InChIKey NUIURNJTPRWVAP-UHFFFAOYSA-N
IARC 2B (Vol. 1, Sup 7) 1987
NIST Chemistry Reference [1,1'-Biphenyl]-4,4'-diamine, 3,3'-dimethyl-(119-93-7)
EPA Tshuaj Registry System 3,3'-Dimethylbenzidine (119-93-7)
 
Cov ntaub ntawv kev nyab xeeb
Hazard Codes T,N,F
Risk Statements 45-68-51/53-22-11
Cov lus hais txog kev nyab xeeb 53-45-61-16
RIDADR UN 3082 9/PG 3
OEL Qab nthab: 0.02 mg/m3 [60-minute] [skin]
WGK Germany 3
RTECS 1225 000 dr hab
F 8
TSCA Yog lawm
HazardClass 6.1(b)
PackingGroup III
HS Code 29215900
Cov Ntaub Ntawv Muaj Xwm Ceev 119-93-7(Cov ntaub ntawv muaj phom sij)
Toxicity aub, LDLo, qhov ncauj, 600mg / kg (600mg / kg), Archiv fuer Experimentelle Pathology und Pharmakologie. Vol. 58 ,pw. 167, 1907 ib.
 
MSDS Cov Ntaub Ntawv
Tus kws kho mob Lus
C.I. 37230 Lus Askiv
SigmaAldrich Lus Askiv
ACROS Lus Askiv
ALFA Lus Askiv
 
Kev siv O-Tolidine thiab Synthesis
Kev piav qhia o-Tolidine, tseem hu ua orthotolidine los yog 2-tolidine, yog cov tshuaj sib xyaw nrog cov mis molecular (C6H4(CH3)NH2)2. Nws yog ib tug dawb mus rau reddish-xim, combustible, aromatic amine uas emits tshuaj lom fumes ntawm nitrogen oxides thaum rhuab mus decomposition. Ob peb isomers paub; cov 3-tolidine derivative kuj tseem ceeb rau kev lag luam. Nws yog cov xim tsis muaj xim txawm tias cov qauv coj mus muag feem ntau muaj xim. Nws yog me ntsis soluble hauv dej. Nws tsim cov ntsev nrog cov kua qaub, xws li hydrochloride, uas yog muag. 2-Tolidine tuaj yeem tsim los ntawm kev hloov kho benzidine los ntawm hydrazine derivative tau los ntawm 2-nitrotoluene.
Chemical Properties o-Tolidine yog dawb mus rau reddish siv lead ua los yog hmoov thiab muaj ib tug zoo li aniline tsw. Nws yog soluble hauv cawv, ether, thiab dilute acid, tab sis tsuas yog me ntsis soluble hauv dej. Nws muaj qhov nyiam ua kom tsaus ntuj thaum raug huab cua thiab feem ntau siv rau hauv daim ntawv muab tshuaj txhuam los yog ntub cov ncuav mog qab zib. Qhov kev sib xyaw no ua haujlwm tseem ceeb hauv kev tsim cov dyes ntau.
Siv o-Tolidine yog siv dav hauv kev tsim cov dyes, tshwj xeeb tshaj yog nyob rau hauv kev tsim cov azo soluble dyes thiab insoluble pigments rau textile, tawv, thiab ntawv sectors. Tsis tas li ntawd, Nws kuj yog siv los ua ib qho rhiab colorimetric reagent rau kev tsom xam ntawm kub thiab dawb chlorine hauv dej.
Siv 3,3'-Dimethylbenzidine siv rau kev npaj cov khoom siv polyimide thiab epoxy resin.
Kev npaj Muaj ob txoj hauv kev siv los ua o-Tolidine. Thawj txoj kev suav nrog kev txo qis ortho-nitrotoluene rau 1, 2-diorthotolylhydrazine, uas tom qab ntawd rov kho cov kua qaub. Qhov thib ob txoj kev yuav txo tau o-nitrotoluene siv zinc plua plav thiab caustic soda, ces converting lub resulting hydrazotoluene rau o-Tolidine los ntawm boiling nws nrog hydrochloric acid. Thaum ib qho ntawm cov txheej txheem no tiav lawm, o-Tolidine tuaj yeem raug muab rho tawm thiab ua kom huv los ntawm cov txheej txheem xws li hnyav extraction thiab recrystallization.
Txhais ChEBI: 3,3'-Dimethylbenzidine yog ib tug tswv cuab ntawm biphenyls.
Kev piav qhia dav dav 3,3'-dimethylbenzidine tshwm li dawb mus rau reddish crystals los yog crystalline hmoov los yog ib lub teeb tan hmoov. (NTP, 1992)
Cua & Dej Reactions Insoluble hauv dej.
Reactivity Profile CI 37230 yog rhiab heev rau raug lub teeb. Tej zaum yuav rhiab heev rau lub sij hawm raug rau huab cua. Lub hauv paus tsis muaj zog uas tsim cov ntsev nrog hydrochloric acid lossis sulfuric acid. CI 37230 tuaj yeem ua acetylated. Incompatible nrog cov neeg ua haujlwm muaj zog.
Hazard Qhov muag, zais zis thiab lub raum irritant, zais zis mob cancer, thiab methemoglobinemia. Ua tau carcinogen.
Health Hazard Cov ntaub ntawv ntawm toxicity thiab carcinogenicity ntawm o-tolidine yog tsawg heev. o-Tolidine feem ntau muaj lwm yam kab mob biphenylamine. Nws cov qauv thiab tshuaj lom neeg zoo ib yam li cov benzidine. Yog li ntawd, cov tshuaj toxicity yuav tsum zoo ib yam li cov benzidine.
o-Tolidine yog nqus mus rau hauv lub cev los ntawm daim tawv nqaij, ua pa, thiab gastrointestinaltract. Qhov mob qhov ncauj thiab dermal toxicity yog nruab nrab hauv cov tsiaj sim. Tus nqi ntawm qhov ncaujLD50 hauv nas yog nyob rau hauv thaj tsam ntawm 400 mg / kg.
o-Tolidine tsim cov qog nqaij hlav zais zis hauv cov tshuaj ntsuam xyuas. Tsis tas li ntawd, cov qog nqaij hlav hauv lwm cov ntaub so ntswg tau sau tseg hauv qee cov tsiaj. ACGIH teev cov khoom no raws li kev xav tias tib neeg carcinogen.
Hluav Taws Xob Flash point cov ntaub ntawv rau CI 37230 tsis muaj; Txawm li cas los xij, CI 37230 yog tej zaum combustible.
Kev ruaj ntseg Profile Cov ntaub ntawv pov thawj carcinogen nrog kev sim carcinogenic thiab cov ntaub ntawv tumorigenic. Tshuaj lom los ntawm txoj kev intraperitoneal. Muaj tshuaj lom los ntawm kev noj tshuaj. Human mutation data qhia. Thaum rhuab mus rau decomposition nws emits cov pa phem ntawm NOx.
Ntxim yuav nphav raug Tshaj li 75% ntawm o-tolidine yog siv los ua cov xim thiab ua ib qho nruab nrab hauv kev tsim cov khoom siv roj hmab, dyestuffs, pigments thiab tshuaj tua kab. Kwv yees li ntawm 20% ntawm o-tolidine yog siv los tsim cov polyurethane-based high-strength elastomers, coatings, thiab tawv yas. o-Tolidine kuj tau siv me me hauv cov khoom siv tshuaj chlorine los ntawm cov tuam txhab dej thiab cov tswv pas dej da dej. Siv los ua ib tus neeg saib xyuas kuaj ntshav los kuaj ntshav.
Carcinogenicity 3,3′-Dimethylbenzidine yog qhov tsim nyog xav tias yuav yog tib neeg carcinogen raws li cov pov thawj txaus ntawm carcinogenicity los ntawm kev tshawb fawb hauv cov tsiaj sim.
Kev xa khoom UN2811 Toxic solids, organic, nos, Hazard Class: 6.1; Cov ntawv lo: 6.1-Cov ntaub ntawv muaj kuab lom, Kev Siv Lub Npe Yuav Tsum Tau. UN3077 Environmentally hazardous substances, solid, nos, Hazard class: 9; Cov ntawv lo: 9-Lwm yam khoom siv phom sij, Kev Siv Lub Npe Yuav Tsum Tau.
Txoj Kev Purification Dissolve cov tolidine hauv * benzene los ntawm percolation los ntawm ib kem ntawm activated alumina thiab crystallize nws los ntawm * benzene / tsiaj ether. [Beilstein 13 IV 410.]
Kev tsis sib haum xeeb Tsis sib haum nrog oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, thiab lwm yam); kev sib cuag tej zaum yuav ua rau hluav taws kub los yog tawg. Khaws kom deb ntawm cov ntaub ntawv alkaline, muaj zog hauv paus, muaj zog acids, oxoacids, epoxides, muaj zog txo cov neeg ua haujlwm.
Pov tseg pov tseg Dissolve nyob rau hauv flammable hnyav thiab tshuaj tsuag rau hauv firebox ntawm ib tug incinera tor nruab nrog afterburner thiab scrubber. Tham nrog cov koom haum tswj hwm ib puag ncig rau kev taw qhia txog kev coj ua pov tseg. Lub tshuab hluav taws xob ntawm cov khoom pov tseg uas muaj cov kab mob no (Ntau dua lossis sib npaug li 100 kg / mo) yuav tsum ua raws li EPA cov cai tswj hwm kev khaws cia, kev thauj mus los, kev kho, thiab kev pov tseg pov tseg.
 
O-Tolidine Kev Npaj Cov Khoom Siv Thiab Cov Khoom Raw
Cov khoom siv raw 2-Nitrotoluene-->6-Amino-4-hydroxy-2-naphthalenesulfonic acid-->O-Tolidine
Cov khoom npaj disodium 3-[[4'-[(6-amino-1-hydroxy-3-sulphonato-2-naphthyl)azo]-3,3'-dimethoxy[1,1'-biphenyl]-4-yl]azo]-4-hydroxynaphthalene-1-sulphonate-->N,N'-(3,3'-Dimethyl-4,4'-biphenyldiyl)bis(3-oxobutanamide)-->DIRECT BLUE 15-->Sieber Linker-->ACID RED 114-->5-Amino-4-hydroxy-3-[[4'-[(1-hydroxy-4-sulfonaphthalen-2-yl)azo]-3,3'-dimethyl[1,1'-biphenyl]-4-yl]azo]-2,7-naphthalenedisulfonic acid trisodium salt-->N,N'-(3,3'-Dimethyl-4,4'-biphenyldiyl)bis(3-oxobutanamide)-->1,3,6-Naphthalenetrisulfonic acid, 8-hydroxy-7-[[4'-[(2-hydroxy-1-naphthalenyl)azo]-3,3'-dimethyl[1,1'-biphenyl]-4-yl]azo]-, trisodium salt-->BRILLIANT PURPURIN R-->trisodium 5-amino-3-[[4'-[(6-amino-1-hydroxy-3-sulphonato-2-naphthyl)azo]-3,3'-dimethyl[1,1'-biphenyl]-4-yl]azo]-4-hydroxynaphthalene-2,7-disulphonate-->Direct Black 24-->DIRECT ORANGE 6-->Evans Blue-->N,N'-(3,3'-dimethyl[1,1'-biphenyl]-4,4'-diyl)bis(3-hydroxynaphthalene-2-carboxamide)-->Direct Black 154-->Direct Brown 222-->C.I. Direct Orange 31-->OXAMINE BLUE 4R-->Direct Brown 146-->DIRECT DUA 2

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