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6,8-Nonadien-2-ib, 8-methyl-5-(1-methylethyl)-, (5S,6E)

6,8-Nonadien-2-ib, 8-methyl-5-(1-methylethyl)-, (5S,6E)

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6,8-Nonadien-2-ib, 8-methyl-5-(1-methylethyl)-, (5S,6E)- Cov ntaub ntawv yooj yim
Khoom npe: 6,8-Nonadien-2-ib, 8-methyl-5-(1-methylethyl)-, (5S,6E)-
Synonyms: 6,8-Nonadien-2-ib, 8-methyl-5-(1-methylethyl)-, (5S,6E)-;(S,E){{ 10}Methyl{11}}(1-methylethyl)-6,8-nonadien{15}}ib;[S,6E,(+)]-5- Isopropyl-8-methyl-6,8-nonadien-2-ib;8-Nonadien-2-ib, 8-Methyl{26}} (1-Methylethyl)-, (5S,6E)-; Solanone DISCONTINUED;(5S,6E)-8-Methyl-5-(1-Methylethyl)-6, 8-Nonadien-2-Ib; D-Solanone
CAS: 1937-54-8
MF: C13H22O
MW: 194.31
EINECS:  
Khoom Categories:  
Mol File: 1937-54-8.mol
6,8-Nonadien-2-one, 8-methyl-5-(1-methylethyl)-, (5S,6E)- Structure
 
6,8-Nonadien-2-ib, 8-methyl-5-(1-methylethyl)-, (5S,6E)- Cov Khoom Siv Tshuaj
alpha D23 +13.6 degree (zoo)
Boiling point bp 1 60 degree
ceev d420 0.870
Refractive Index nD20 1.4755
EPA Tshuaj Registry System 6,8-Nonadien-2-ib, 8-methyl-5-(1-methylethyl)-, (5S,6E)- (1937-54-8)
 
Cov ntaub ntawv kev nyab xeeb
 
MSDS Cov Ntaub Ntawv
 
 
6,8-Nonadien-2-ib, 8-methyl-5-(1-methylethyl)-, (5S,6E)- Kev Siv Thiab Synthesis
Siv Solanone yog siv los ua cov tshuaj tsw qab hauv cov luam yeeb. Cov compound tuaj yeem xaiv los ntawm Nicotiana glutinosa L. nplooj.
Txoj Kev Purification Purify solanone los ntawm lub tshuab nqus tsev distillation thiab khaws cia rau hauv cov khoom ntim kaw [Kohda & Sato J Chem Soc, Chem Commun 951 1981]. Nws muaj UV (hexane) ntawm max 230nm (11,800). Lub semicarbazone crystallises los ntawm aqueous EtOH los yog toluene nrog m 160.5-161.5o. [Johnson et al. J Org Chem 30 2918 1965.]
 
6,8-Nonadien-2-ib, 8-methyl-5-(1-methylethyl)-, (5S,6E)- Kev Npaj Khoom Thiab Raw Khoom
Cov khoom nyoos (3R)-6-methyl-3-propan-2-yl-7-oxabicyclo[4.1.0]heptane-->Hexanal, 2-(1-methylethyl)-5-oxo-, (2S)--->(+)-P-MENTH-1-ENE-->DIETHYL (2-METHYLALLYL)PHOSPHONATE 97-->2-BROMOPROPENE-->(+)-Dipentene

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