3-Methyl-2-butanone

3-Methyl-2-butanone

Khoom Taw qhia

3-Methyl-2-butanone Cov ntaub ntawv yooj yim
tsw
Khoom npe: 3-Methyl-2-butanone
Synonyms: ISOPROPYL METHYL KETONE; METHYL ISOPROPYL KETONE;3-METHYL-2-BUTANONE;3-Methylbutanone;1,1-Dimethyl acetone;MIPK;2-Acetylpropane;{{6 }}Butanone, 3-methyl-
CAS: 563-80-4
MF: C5H10O
MW: 86.13
EINECS: 209-264-3
Khoom Categories: Amber iav fwj; Humulus lupulus (Hops); Kev Tshawb Fawb Kev Noj Qab Haus Huv; Phytochemicals los ntawm Nroj Tsuag (Food / Spice / Tshuaj ntsuab); Reagent; Solvent Fwj; Kev Lag Luam / Tshuaj Tshuaj Zoo; Organics; ketone; Cov Khoom Siv Ntim Ntim; Cov Khoom Siv Tshuaj
Mol File: 563-80-4.mol
3-Methyl-2-butanone Structure
 
3-Methyl-2-butanone Cov Khoom Siv Tshuaj
Melting point -92 degree (lit.)
Boiling point 94-95 degree (lit.)
ceev 0.805 g/mL ntawm 25 degree (lit.)
vapor siab 53.33 hPa (19.9 degree)
Refractive Index n20 / D 1.388 (lit.)
Fp 6 degree
cia temp. Khaws hauv qab +30 degree .
solubility dej: soluble 8.21g / L ntawm 20 degree
daim ntawv Ua kua
xim Ntshiab xim tsis muaj xim
tsw ntawm 0.10?%?in?dipropylene glycol. camphor
Odor Threshold 0.5ppm
tawg txwv 1.5-9%(V)
Dej Solubility 6 g/L (20 ºC)
Merck 14,6090
BRN 1071238
Kev txwv tsis pub dhau TLV-TWA 700 mg/m3(200 ppm); STEL 875 mg/m3(250 ppm) (ACGIH).
Dielectric tsis tu ncua 16.57
InChIKey SYBYTAAJFKOIEJ-UHFFFAOYSA-N
LogP 2.29 ntawm 20 degree
CAS DataBase Reference 563-80-4(CAS DataBase Reference)
NIST Chemistry Reference 2-Butanone, 3-methyl-(563-80-4)
EPA Tshuaj Registry System Methyl isopropyl ketone ({0}})
 
Cov ntaub ntawv kev nyab xeeb
Hazard Codes F
Risk Statements 11-67
Cov lus hais txog kev nyab xeeb 9-16-33
OEB A
OEL TWA: 200 ppm (705 mg/m3)
RIDADR UN 2397 3/PG 2
WGK Germany 1
RTECS TSI 910000
Autoignition Kub 475 degree
Ceeb toom Heev Flammable
TSCA Yog lawm
HazardClass 3
PackingGroup II
HS Code 29141990
Cov Ntaub Ntawv Muaj Xwm Ceev 563-80-4(Cov ntaub ntawv muaj phom sij)
Toxicity LD50 nyob rau hauv cov txiv neej nas: 29. 86 mmol/kg (Tanii)
 
MSDS Cov Ntaub Ntawv
Tus kws kho mob Lus
3-Methyl-2-butanone Lus Askiv
SigmaAldrich Lus Askiv
ACROS Lus Askiv
ALFA Lus Askiv
 
3-Methyl-2-butanone Siv Thiab Synthesis
tsw Diffusive, ethereal-camphoraceous tsw, qab ntxiag nyob rau hauv dilution, me ntsis pungent-choking thaum concentrated. Ethereal-vinous saj, tab sis me ntsis iab ntawm qhov siab tshaj 50 ppm.
Kev piav qhia MIPK yog cov kua tsis muaj xim nrog cov ntxhiab tsw acetone. Molecular hnyav {{0}}.15; Specification gravity(H2O:1) 5 0.81; Boiling point=93 degree . Freezingpoint 5 2 92 degree ; Vapor siab 5 42 mmHg ntawm 20 degree ; Flashpoint 5 6 degree ; Autoignition kub 5 475 degree . Explosivelimits: LEL 5 1.2%; UEL 5 8%. Kev txheeb xyuas qhov phom sij (raws li NFPA-704 M Rating System): Kev Noj Qab Haus Huv 1, Flammability 4, Reactivity 0. me ntsis soluble hauv dej; solubility 5 0.5% ntawm 20 degree .
Chemical Properties CLEAR COLORLESS LIQUID
Chemical Properties MIPK yog cov kua tsis muaj xim nrog cov ntxhiab tsw acetone. 3-Methyl-2-butanone yog cov kua tsis muaj xim uas muaj cov yam ntxwv ketone tsws. Lub tertiary carbon atom tau yooj yim oxidized thiab qhov tshwm sim hydroperoxide (mp 26 - 27 degree) tuaj yeem tsim los ntawm lub hauv paus-catalyzed huab cua oxidation.
Siv Methyl isopropyl ketone (MIPK) yog siv asa hnyav rau lacquers.
Siv 3-Methyl-2-butanone yog siv rau kev sib txuas ntawm heterocyclic compounds thiab tseem ceeb hauv nruab nrab ntawm cov tshuaj. Nws yog siv los ua ib qho hnyav hnyav.
Siv Cov kuab tshuaj rau nitrocellulose lacquers. 3-Methyl-2-butanone yog ua haujlwm feem ntau ua ib qho nruab nrab rau kev tsim tshuaj, tshuaj tua kab mob, thiab tshuaj pleev xim ua ntej. Nws kuj yog siv nyob rau hauv lub synthesis ntawm roj hmab auxiliaries thiab rau cov xaiv extraction ntawm tsawg ntiaj teb ntsiab.
Txhais ChEBI: 3-Methylbutan-2- ib qho yog ketone.
Kev npaj 3-Methyl-2-butanone yog tsim los ntawm oxidation ntawm Methyl-iso-propylcarbinol (2-Methyl-3-butanol).
Kev piav qhia dav dav Cov kua uas tsis muaj xim nrog cov ntxhiab tsw qab ntxiag. Flash point hauv qab 70 degree F. Tsawg ntom dua dej. Tej zaum yuav muaj tshuaj lom los ntawm kev nqus pa thiab nqus ntawm daim tawv nqaij. Siv ua kuab tshuaj.
Cua & Dej Reactions Cov nplaim taws heev. Soluble hauv dej.
Reactivity Profile Ketones, xws li 3-Methyl-2-butanone, yog reactive nrog ntau cov kua qaub thiab cov hauv paus liberating cov cua sov thiab cov pa hluav taws xob (xws li H2). Cov cua sov yuav txaus los pib hluav taws nyob rau hauv qhov tsis muaj kev cuam tshuam ntawm ketone. Ketones hnov ​​​​mob nrog txo cov neeg ua haujlwm xws li hydrides, alkali hlau, thiab nitrides los tsim cov pa roj (H2) thiab cua sov. Ketones tsis sib haum nrog isocyanates, aldehydes, cyanides, peroxides, thiab anhydrides. Lawv hnov ​​​​mob hnyav nrog aldehydes, HNO3, HNO3 + H2O2, thiab HClO4.
Hazard Cov khoom siv tshuaj lom. Embryo/fetal puas thiab neonatal toxicity.
Health Hazard Irritating rau lub qhov muag, qhov ntswg, caj pas, qhov ua pa sab sauv, thiab daim tawv nqaij.
Health Hazard Cov tshuaj lom neeg mob hnyav los ntawm kev raug rau cov vapors ntawm MIPK yog narcosis thiab khaus ntawm lub qhov muag, daim tawv nqaij, thiab cov kab mob ua pa.Nyob rau hauv cov luav cov tsos mob ntawm 100 mg fora 24- teev raug mob me me hauv qhov muag, thaum 500 mg yog nruab nrab. ntawm daim tawv nqaij. Cov ntaub ntawv toxicity ntawm cov tshuaj no tsis tshua muaj heev. Feem ntau, nws cov tshuaj toxicity tsawg thiab cov tsos mob narcosis nyob rau hauv tib neeg tej zaum yuav hnov ​​tsuas yog nyob rau hauv heev concentrations. Hauv guinea npua exposureto 5000 ppm ua rau coma.
Hluav Taws Xob Kev phom sij tshwj xeeb ntawm combustion khoom: Acrid pa luam yeeb thiab pa taws
Flammability thiab Explosibility Cov nplaim taws heev
Kev ruaj ntseg Profile Tshuaj lom los ntawm kev noj tshuaj. Mob me me los ntawm kev nqus pa thiab kev sib cuag ntawm daim tawv nqaij. Cov ntaub ntawv hloov pauv tau tshaj tawm. Ib daim tawv nqaij thiab qhov muag irritant. Flammable thaum raug tshav kub los yog nplaim taws; tuaj yeem cuam tshuam nrog cov khoom siv oxidizing. Thaum rhuab mus rau decomposition nws emissions pa luam yeeb thiab irritating fumes.
Ntxim yuav nphav raug Cov ketone no yog siv los ua cov kuab tshuaj rau nitrocellulose lacquers.
Kev pab thawj zaug Yog hais tias cov tshuaj no nkag mus rau hauv lub qhov muag, tshem tawm ib qho kev sib cuag lo ntsiab muag ib zaug thiab irrigate tam sim ntawd rau tsawg kawg yog 15 feeb, qee zaus nqa lub hau sab sauv thiab qis dua. Nrhiav kev kho mob tam sim ntawd. Yog tias cov tshuaj no kis rau ntawm daim tawv nqaij, tshem tawm cov khaub ncaws tsis huv thiab ntxuav tam sim nrog xab npum thiab dej. Nrhiav kev kho mob tam sim ntawd. Yog tias cov tshuaj no tau nqus tau lawm, tshem tawm ntawm qhov raug, pib ua pa cawm siav (siv kev ceev faj thoob ntiaj teb, suav nrog daim npog qhov ncauj resuscitation) yog tias ua pa tau nres thiab CPR yog tias lub plawv nres. Hloov tam sim ntawd mus rau qhov chaw kho mob. Thaum cov tshuaj no tau nqos lawm, mus ntsib kws kho mob. Muab dej ntau thiab ua kom ntuav. Tsis txhob ua rau tus neeg tsis nco qab ntuav.
khaws cia Xim Code-Red: Flammability Hazard: Khaws cia rau hauv qhov chaw cia cov kua hluav taws xob los yog lub txee tso cai kom deb ntawm qhov hluav taws kub thiab cov khoom siv corrosive thiab reactive.Ua ntej ua hauj lwm nrog cov tshuaj no koj yuav tsum tau kawm txog nws txoj kev tuav thiab khaws cia. Ua ntej nkag mus rau hauv qhov chaw kaw qhov chaw uas cov tshuaj no tuaj yeem tshwm sim, xyuas kom paub tseeb tias tsis muaj cov khoom tawg. Khaws cov thawv kaw nruj nreem rau hauv qhov chaw txias, qhov cua zoo kom deb ntawm aldehydes. Qhov chaw ntawm qhov hluav taws kub, xws li haus luam yeeb thiab qhib nplaim taws, txwv tsis pub qhov twg methyl isopropylketone siv, tuav, lossis khaws cia rau hauv ib qho uas yuav ua rau muaj hluav taws kub lossis tawg. Siv cov cuab yeej thiab cov khoom siv tsis muaj teeb meem nkaus xwb, tshwj xeeb tshaj yog thaum qhib thiab kaw cov ntim ntawm methyl isopropyl ketone. Txhua qhov chaw siv methyl isopropyl ketone siv, tuav, tsim, lossis khaws cia, siv cov khoom siv hluav taws xob tawg thiab cov khoom siv.
Kev xa khoom UN23973-Methylbutan-2-ib, Hazard Class: 3; Cov ntawv lo: 3-Flammable kua.
Txoj Kev Purification Reflux lub ketone nrog me ntsis KMnO4. Fractionate nws los ntawm ib sab spinning-band, qhuav nrog CaSO4 thiab distil nws. [Beilstein 1 IV 3287.]
Kev tsis sib haum xeeb Cov vapors tuaj yeem tsim tawg sib xyaw nrog huab cua. Ketones tsis sib haum nrog oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, thiab lwm yam); kev sib cuag tej zaum yuav ua rau hluav taws kub los yog tawg. Khaws kom deb ntawm cov ntaub ntawv alkaline, muaj zog hauv paus, muaj zog acids, oxoacids, epoxides, nitrated amines, azo, diazo, azido tebchaw, carbamates, organic cyanates
Pov tseg pov tseg Dissolve los yog sib tov cov khoom nrog ib tug combustible solvent thiab hlawv nyob rau hauv ib tug chemical incinerator nruab nrog ib tug afterburner thiab scrubber. Tag nrho tsoom fwv teb chaws, xeev, thiab cheeb tsam ib puag ncig cov cai yuav tsum tau ua raws li.
 
3-Methyl-2-butanone Kev Npaj Khoom Siv Thiab Cov Khoom Raw
Cov khoom nyoos Oxygen-->Isobutyraldehyde-->2-Methyl-2-butanol-->2,3-dibromo-2-methylbutane-->DL-Mevalonolactone-->Dehydromevalonolactone-->Isoprene
Cov khoom npaj Imazaquin acid-->1,3,3-TRIMETHYLINDOLINOBENZOPYRYLOSPIRAN-->2,6-DIMETHYL-3,5-HEPTANEDIONE-->1,2,5-OXADIAZOLE-3-CARBOXYLIC ACID-->3-METHYL-1,2,5-OXADIAZOLE-->(1,2-DIMETHYL-PROPYL)-HYDRAZINE-->Imazamox-->Bromoform-->2-Amino-2,3-dimethylbutyronitrile-->2-Butanone, 3-methyl-, oxime-->Ethyl isobutyrylacetate-->N-AMYL ISOPROPYL KETONE-->2,3-DIMETHYLDECANE-->2,3,3-Trimethyl-5-methoxy-3H-indole

Cim npe nrov: 3-methyl-2-butanone, Tuam Tshoj 3-methyl-2-butanone manufacturers, lwm tus neeg, Hoobkas

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