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2,6,10,10-Tetramethyl-1-oxaspiro[4.5]dec-6-ene

2,6,10,10-Tetramethyl-1-oxaspiro[4.5]dec-6-ene

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2,6,10,10-Tetramethyl-1-oxaspiro[4.5]dec-6-ene Cov ntaub ntawv yooj yim
Khoom npe: 2,6,10,10-Tetramethyl-1-oxaspiro[4.5]dec-6-ene
Synonyms: 2,6,10,10-tetramethyl-1-oxaspiro[4.5]dec-6-en;FEMA 3774;2,6,10,10-TETRAMETHYL-1-OXASPIRO [4.5]DEC-6-ENE;2,6,10,10-TETRAMETHYL-1-OXASPIROL[4,5]DEC-6-ENE;spiroxide;THEASPIRAN;(+/- )-THASPIRANE; THEASPIRANE
CAS: 36431-72-8
MF: C13H22O
MW: 194.31
EINECS: 253-031-9
Khoom Categories: C12 rau C20+; Tsev Blocks; Flavor; Chemical Synthesis; Furans; Heterocyclic Building Blocks
Mol File: 36431-72-8.mol
2,6,10,10-Tetramethyl-1-oxaspiro[4.5]dec-6-ene Structure
 
2,6,10,10-Tetramethyl-1-oxaspiro[4.5]dec-6-ene Chemical Properties
Boiling point 68-72 degree 3 mm Hg (lit.)
ceev 0.931 g/mL ntawm 25 degree (lit.)
Refractive Index n20/D 1.438 (lit.)
FEMA 3774|THEASPIRANE
Fp 195 degree F
cia temp. Muab kaw rau hauv qhuav, Chav Kub
solubility Chloroform (me ntsis), Ethyl Acetate (me ntsis)
daim ntawv Roj
xim Tsis muaj xim
tsw ntawm 1.00 % hauv dipropylene glycol. tshuaj yej herbal ntsuab ntub luam yeeb nplooj hlau metallic woody ntsim
Hom tshuaj tsw qab tshuaj ntsuab
JECFA Number 1238
BRN 1424383
LogP 4.14
CAS DataBase Reference 36431-72-8(CAS DataBase Reference)
EPA Tshuaj Registry System 1-Oxaspiro[4.5]dec-6-ene, 2,6,10,10-tetramethyl- (36431-72-8)
 
Cov ntaub ntawv kev nyab xeeb
Cov lus hais txog kev nyab xeeb 24/25
WGK Germany 2
HS Code 2932190090
 
MSDS Cov Ntaub Ntawv
Tus kws kho mob Lus
SigmaAldrich Lus Askiv
 
2,6,10,10-Tetramethyl-1-oxaspiro[4.5]dec-6-ene Siv Thiab Synthesis
Kev piav qhia Theaspirane yog cov kua daj daj daj, soluble hauv cawv lossis propylene glycol. Nws muaj cov tshuaj yej dub ib txwm aroma, qab zib saj, thiab sib xyaw aroma yam ntxwv xws li fruity thiab woody aromas. Theaspirane yog qib high-qib monomeric tshuaj tsw qab dav siv thoob ntiaj teb.
Chemical Properties Theaspirane yog fruity, woody, sweetish thiab ionone zoo li camphoraceous.
Qhov tshwm sim Qhia pom nyob rau hauv Vitis vinifera L., raspberry (Rubus idaecus L.), dawb wine, dub tshuaj yej, daj passion txiv hmab txiv ntoo kua txiv, daj passion txiv hmab txiv ntoo, txiv hmab txiv ntoo, quince, cherimoya (Annona cherimola) thiab dub chokeberry (Aronia melanocarpa Ell.).
Yam ntxwv 1. Pom muaj nyob rau hauv cov nplooj luam yeeb.
2. Ib txwm muaj nyob rau hauv cov txiv hmab txiv ntoo daj, qab zib-scented osmanthus, raspberry.
3. Cov tshuaj yej spiro hauv cov luam yeeb los ntawm kev degradation ntawm carotene.
4. Muaj ob lub isomers, ib qho yog woody, camphor aroma, thiab lwm yam yog naphthalene-zoo li tsw.
Txhais ChEBI: Theaspirane yog ib tug norisoprenoid nrog forumula C13H22O uas yog ib tug tsw tivthaiv muaj nyob rau hauv ntau yam tseem ceeb roj xws li raspberry roj thiab passion txiv hmab txiv ntoo roj. Nws muaj lub luag haujlwm ua cov tshuaj tsw qab, tus neeg sawv cev flavoring thiab cov roj tsis hloov pauv. Nws yog ib qho oxaspiro compound, ib qho tsis muaj zog organic compound, norisoprenoid thiab olefinic compound.
Aroma pib qhov tseem ceeb Aroma yam ntxwv ntawm 1.
Saj pib qhov tseem ceeb Cov yam ntxwv saj ntawm 10 ppm: txias ntsuab, mentholic, woody Pine thiab cedar-zoo li nrog ib tug tshuaj ntsuab nuance.
Synthesis Reference (cov) Tetrahedron Letters, 26, p. 4637, 1985 ibDOI: 10.1016/S0040-4039(00)98772-0
Biochem/physiol Actions Cov ntxhiab tsw ntawm 1.0%

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