Khoom

Tsev / Khoom / Ether

Allyl Glycidyl Ether

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Khoom Taw qhia

Allyl glycidyl ether Cov ntaub ntawv yooj yim

Kev piav qhia Kev Npaj Siv

Khoom npe:	Allyl glycidyl ether
Synonyms:	[(2-propenyloxy)methyl]-oxiran;[(2-Propenyloxy)methyl]oxirane;[(2-Propenyloxy)-methyl]oxirane;[(2-propenyloxy) methyl]-Oxirane;1-(allyloxy)-2,3-epoxy-propan;1-Allilossi-2,3 epossipropano;1-allilossi{ {15}},3epossipropano;1-Allyl{18}},3-epoxypropane
CAS:	106-92-3
MF:	C6H10O2
MW:	114.14
EINECS:	203-442-4
Khoom Categories:	Tej yam yooj yim 3-Nplhaib koom ua ke; Oxiranes; Kev lag luam / Tshuaj zoo; K00001
Mol File:	106-92-3.mol

Allyl glycidyl ether Chemical Properties

Melting point	-100 degree
Boiling point	154 degree (lit.)
ceev	0.962 g/mL ntawm 25 degree (lit.)
vapor ceev	3.9 (vs huab cua)
vapor siab	4.7 hli Hg (25 degree)
Refractive Index	n20/D 1.433 (lit.)
Fp	135 degree F
cia temp.	Khaws ntawm<= 20°C.
solubility	50g / L (20 degree)
daim ntawv	Ua kua
Specific Gravity	0.962
xim	Ntshiab xim tsis muaj xim
Dej Solubility	50 g/L (20 ºC)
BRN	105871
Henry's Law Constant	(x 10^-6atm ua³/mol): 3.83 ntawm 20 degree (kwv yees - xam los ntawm dej solubility thiab vapor siab)
Kev txwv tsis pub dhau	NIOSH REL: TWA 5 ppm (22 mg/m³, STEL 10 ppm (44 mg/m³), IDLH 50 ppm; OSHA PEL: qab nthab 10 ppm; ACGIH TLV: TWA 5 ppm, STEL 10 ppm.
Kev ruaj ntseg:	ruaj khov. Hluav taws kub. Incompatible nrog muaj zog oxidizing neeg sawv cev, acids, bases. Tej zaum yuav tsim peroxides nyob rau hauv cia yog nyob rau hauv kev sib cuag nrog huab cua.
InChIKey	LSWYGACWGAICNM-UHFFFAOYSA-N
LogP	0.45 ntawm 25 degree
CAS DataBase Reference	106-92-3(CAS DataBase Reference)
NIST Chemistry Reference	Oxirane, [(2-propenyloxy)methyl]-({2}})
EPA Tshuaj Registry System	Allyl glycidyl ether ({0}})

Cov ntaub ntawv kev nyab xeeb

Hazard Codes	Xn
Risk Statements	10-20/22-37/38-40-41-43-52/53-62-68
Cov lus hais txog kev nyab xeeb	24/25-26-36/37/39-61
RIDADR	UN 2219 3/PG 3
WGK Germany	3
RTECS	RR0875 000 Nws
Autoignition Kub	264 degree
TSCA	Yog lawm
HazardClass	3
PackingGroup	III
HS Code	29109000
Cov Ntaub Ntawv Muaj Xwm Ceev	106-92-3( Cov ntaub ntawv muaj phom sij)
Toxicity	LD50 qhov ncauj hauv luav: 922 mg/kg LD50 dermal luav 2550 mg/kg
IDLA	50 ppm

Tus kws kho mob	Lus
Allyl 2, 3-epoxypropyl ether	Lus Askiv
SigmaAldrich	Lus Askiv
ACROS	Lus Askiv
ALFA	Lus Askiv

Allyl glycidyl ether Siv thiab Synthesis

Kev piav qhia	Allyl glycidyl ether yog cov kua tsis muaj xim clycidyl ether nrog cov tsw qab ntxiag. Lub compound yog insoluble nyob rau hauv dej thiab tsawg ntom dua dej, yog li ntawd yooj yim ntab rau hauv dej. Thaum noj los yog nqus tau, allyl glycidyl ether yog tshuaj lom me me. Nws tsis raug cais raws li tib neeg carcinogen.
Kev npaj	Hauv cov tshuaj tiv thaiv condensation, epichlorohydrin thiab allyl cawv yog siv rau hauv kev sib txuas ntawm allyl glycidyl ether.
Siv	Allyl glycidyl ether yog siv nyob rau hauv sealants thiab adhesives. Nws kuj tseem siv rau hauv kev tsim cov polyvinylcaprolactam.
Chemical Properties	kua tsis muaj xim
Chemical Properties	Allyl glycidyl ether yog ib qho ruaj khov, tsis muaj xim, nplaim taws ua kua nrog cov tsw qab ntxiag. Nws yog incompatible nrog muaj zog oxidizers, acids, thiab bases. Nws tuaj yeem tsim peroxides hauv qhov chaw cia yog tias nyob rau hauv kev sib cuag nrog huab cua.
Chemical Properties	Allyl glycidyl ether yog cov kua tsis muaj xim nrog lub zog, tsw qab
Lub cev muaj zog	Ntshiab, tsis muaj kob, dej, combustible kua nrog ib tug muaj zog, qab ntxiag tsw. Tus nqi pib ntawm 47 mg / m³tau tshaj tawm (quoted, Verschueren, 1983).
Siv	Resin intermediate, stabilizer ntawm chlorinated compounds, vinyl resins, thiab roj hmab.
Siv	Allyl glycidyl ether yog monoglycidyl derivative, siv los ua cov tshuaj epoxy reactive rau epoxy resins. Raws li ib qho impurity, nws raug suav hais tias yog tus neeg sawv cev rau cov neeg ua haujlwm hauv kev lag luam yas ua xua rau 3-glycidyloxypropyltrimethoxysilane, epoxy silane compound siv los kho cov tshuaj ntxiv hauv silicone thiab polyurethane.
Siv	Reactive diluent nyob rau hauv epoxy resin systems; stabilizer ntawm chlorinated compounds; kev tsim cov roj hmab
Txhais	Lub sij hawm ntev muaj ib yam dab tsi.
Txoj kev tsim khoom	AGE yog tsim los ntawm condensation ntawm allyl cawv thiab epichlorohydrin nrog tom qab dehydrochlorination nrog caustic los ua lub nplhaib epoxy.
Kev piav qhia dav dav	Cov kua dej tsis muaj xim nrog cov ntxhiab tsw qab ntxiag. Flash point 135 degree F. Me ntsis ntom dua dej thiab insoluble hauv dej. Yog li ntawd floats ntawm dej. Poisonous los ntawm kev noj thiab tshuaj lom me me los ntawm kev nqus pa thiab kev sib cuag ntawm daim tawv nqaij. Heev irritating ntawm daim tawv nqaij thiab ob lub qhov muag. Siv los ua lwm yam tshuaj.
Cua & Dej Reactions	Flamable. Insoluble hauv dej.
Reactivity Profile	Allyl glycidyl ether reacts hnyav nrog oxidizing tus neeg sawv cev. Nws tuaj yeem tsim peroxides. Polymerizes tau yooj yim [Handling Chemicals Safely 1980. p.128].
Hazard	Cov tawv nqaij, qhov muag, thiab cov kab mob ua pa sab saud, thiab dermatitis. Muaj lus nug txog carcinogen.
Health Hazard	Tej zaum yuav ua rau muaj tshuaj lom yog tias nqus tau los ntawm daim tawv nqaij. Kev nqus tau los yog sib cuag nrog cov khoom yuav ua rau khaus lossis hlawv tawv nqaij thiab qhov muag. Hluav taws yuav ua rau khaus, corrosive thiab/los yog cov pa phem. Vapors tuaj yeem ua rau kiv taub hau lossis ua tsis taus pa. Cov dej ntws los ntawm kev tswj hluav taws kub lossis dej dilution tuaj yeem ua rau muaj kuab paug.
Health Hazard	Cov neeg ua haujlwm ua haujlwm raug rau allyl glycidyl ether tsim cov tsos mob hnyav ntawm kev lom lom uas suav nrog, tab sis tsis txwv rau, khaus ntawm qhov muag, liab, mob, qhov muag tsis pom kev, qhov tob tob ntawm daim tawv nqaij kub hnyiab, ua pa; ua rau kev puas tsuaj ntawm cov mucous daim nyias nyias, dermatitis, kub hnyiab tau, ua tsis taus pa luv, mob taub hau, tsaug zog, dullness, xeev siab, ntuav, pulmonary edema, narcosis, muaj peev xwm hematopoietic thiab reproductive teebmeem. Kev raug mob hnyav tuaj yeem ua rau CNS kev nyuaj siab. Lub hom phiaj tseem ceeb ntawm lub cev muaj xws li ob lub qhov muag, tawv nqaij, ua pa, ntshav, thiab lub cev xeeb tub.
Hluav Taws Xob	HIGHLY FLAMMABLE: Yuav tau yooj yim ignited los ntawm tshav kub, sparks los yog nplaim taws. Cov vapors tuaj yeem tsim cov khoom tawg nrog cua. Vapors tuaj yeem mus rau qhov chaw ntawm qhov hluav taws kub thiab rov qab flash. Feem ntau cov vapors hnyav dua li huab cua. Lawv yuav kis tau mus rau hauv av thiab sau rau hauv qhov chaw qis lossis qhov chaw kaw (sewers, hauv qab daus, tanks). Vapor explosion txaus ntshai nyob hauv tsev, sab nraum zoov lossis hauv cov kav dej. Cov dej ntws mus rau hauv cov kav dej yuav ua rau muaj hluav taws kub lossis tawg. Cov thawv ntim khoom tuaj yeem tawg thaum cua sov. Cov kua dej ntau yog sib dua li dej.
Tiv tauj cov tshuaj tsis haum	Allyl glycidyl ether yog monoglycidyl derivative, siv los ua cov tshuaj epoxy reactive rau epoxy resins. Raws li ib qho impurity, nws tau txiav txim siab los ua tus neeg sawv cev hauv kev lag luam yas ua haujlwm ua xua rau 3-glycidyloxypropyl trimethoxysilane, epoxy silane compound siv los kho cov tshuaj ntxiv hauv silicone thiab polyurethane.
Kev ruaj ntseg Profile	Paub tseeb tias tsiaj carcinogen. Tshuaj lom los ntawm kev noj. Muaj tshuaj lom los ntawm kev nqus pa thiab kev sib cuag ntawm daim tawv nqaij. Cov ntaub ntawv hloov pauv tau tshaj tawm. Cov tawv nqaij hnyav thiab qhov muag khaus. Nws tuaj yeem ua rau lub hauv nruab nrab lub paj hlwb kev nyuaj siab thiab pulmonary edema. Cov kua nplaum nplaum thaum raug tshav kub los yog nplaim taws; tuaj yeem cuam tshuam nrog oxidizing cov ntaub ntawv. Txhawm rau tua hluav taws, siv ua npuas ncauj, CO2, tshuaj qhuav qhuav.Thaum rhuab mus rau decomposition nws emits pa taws thiab irritating pa taws. Saib kuj ALLYL COMPOUNDS Allyl glycidyl ether muaj LD50 ntawm 390 mg / kg (nas, qhov ncauj) thiab LD50 ntawm 1600 mg / kg (rat, qhov ncauj). Hauv luav, dermal LD50 yog 2550 mg / kg. Inhalational toxicity tau kwv yees: LC50=270 ppm (nas, 4 h) thiab 670 ppm (nas, 8 h)
Ntxim yuav nphav raug	Siv ua kuab tshuaj thiab emulsifier; ua epoxy resins, chlorinated compounds; thiab roj hmab.
Carcinogenicity	Hauv kev tshawb fawb {{{0}}} xyoo inhalation carcinogenicity kawm hauv Osborne Mendel nas thiab B6C3F1 nas (50 ntawm txhua tus poj niam txiv neej ntawm txhua qhov kev raug mob), cov tsiaj raug nthuav tawm rau qhov ntau ntawm 0, 5, lossis 10 ppm AGE, 6 h / hnub, 5 hnub / lub lis piam. Txawm hais tias qee zaus cov qog ua pa ntawm lub ntsws epithelial tau pom, NTP tau xaus lus cov ntaub ntawv tsuas yog muab pov thawj sib npaug ntawm carcinogenicity hauv txiv neej nas thiab poj niam nas. Tsis muaj pov thawj tau los txhawb kev ua kom muaj carcinogenic hauv cov poj niam nas. Qee cov pov thawj tau muab rau cov lus teb carcinogenic hauv cov txiv neej nas, uas suav nrog peb adenomas ntawm lub ntsws epithelium, dysplasia nyob rau hauv plaub nas, thiab focal basal cell hyperplasia ntawm lub pa epithelium nyob rau hauv lub qhov ntswg passages ntawm xya nas.
Environmental txoj hmoo	Tshuaj lom neeg.Bridié et al. (1979) tau tshaj tawm BOD thiab COD qhov tseem ceeb ntawm 0.06 thiab 1.99 g / g siv cov lim dej lim dej los ntawm cov khoom siv tshuaj tua kab mob lom. Cov txiaj ntsig no tau txiav txim siab siv tus txheej txheem dilution ntawm 20 degree rau lub sijhawm ntawm 5 d. ThOD rau allyl glycidyl ether yog 2.11 g / g. Tshuaj / Lub cev.Hydrolysis ntawm lub nplhaib epoxide zoo li yuav ua rau 1-allyloxy-2, 3- dihydroxypropane (Perez thiab Osterman-Golkar, 2000).
khaws cia	Allyl glycidyl ether yuav tsum tau khaws cia rau hauv qhov chaw txias, tsaus, fi reproof cheeb tsam sib cais los ntawm cov oxidants muaj zog, muaj zog hauv paus, thiab muaj zog acids.
Kev xa khoom	UN2219 Allyl glycidal ether, Hazard Class: 3; Cov ntawv lo: 3-Flammable kua
Kev tsis sib haum xeeb	Tej zaum yuav sib tov sib xyaw nrog cua. Kev sib cuag nrog cov kua qaub lossis cov hauv paus tuaj yeem ua rau tawg polymerization. Kev sib cuag nrog oxidizers lossis amines tuaj yeem ua rau hluav taws kub thiab tawg.
Pov tseg pov tseg	Dissolve los yog sib tov cov khoom nrog ib tug combustible solvent thiab hlawv nyob rau hauv ib tug chemical incinerator nruab nrog ib tug afterburner thiab scrubber. Tag nrho tsoom fwv teb chaws, xeev, thiab cheeb tsam ib puag ncig cov cai yuav tsum tau ua raws li.
Cov kev ceev faj	Thaum siv thiab/lossis tuav cov allyl glycidyl ether, cov neeg ua haujlwm ua haujlwm yuav tsum tsis txhob nyob ze ntawm qhov qhib nplaim taws, sparks, lossis chaw haus luam yeeb. Rau qhov kub siab tshaj 48 degree, siv lub kaw lus kaw qhov cua thiab cov khoom siv hluav taws xob tawg. Cov neeg ua haujlwm yuav tsum siv hnab looj tes tiv thaiv, hnav khaub ncaws tiv thaiv, thiab zam txhua qhov kev sib cuag.