Dodecanedioic Acid

Dodecanedioic Acid

Khoom Taw qhia

Dodecanedioic acid Cov ntaub ntawv yooj yim
Khoom npe: Dodecanedioic acid
Synonyms: DODECANEDIOIC ACID SYNTHESIS; Dodecanedioic aci; Kaum ob alkyl acid; 1.
CAS: 693-23-2
MF: C12H22O4
MW: 230.3
EINECS: 211-746-3
Khoom Categories: Dodecanedioic acid; Kev lag luam / Fine Chemicals; alpha, omega-Alkanedicarboxylic Acids; alpha, omega-Bfunctional Alkanes; Monofunctional & alpha, omega-Bifunctional Alkanes; Aliphatics; Fatty Acid Derivatives & Lipids; 1 Bacts; Glycerol; C12; Carbonyl Compounds; Dicarboxylic Acids; Fatty Acids thiab conjugates; Carboxylic Acids; Chemical Synthesis; Fatty Acyls; Lipids; Organic Building Blocks; bc0001; 693-23-2
Mol File: 693-23-2.mol
Dodecanedioic acid Structure
 
Dodecanedioic acid Cov Khoom Siv Tshuaj
Melting point 127-129 degree (lit.)
Boiling point 245 degree / 10 mmHg (lit.)
ceev 1.15 g / cm33
vapor siab 21 hli Hg (222 degree)
RTECS JR2370000
Refractive Index 1.4437 (kwv yees)
Fp 220 degree
cia temp. Muab kaw rau hauv qhuav, Chav Kub
solubility ethanol: 0.1 g/mL, ntshiab
daim ntawv Pellet los yog hmoov
pka ua 4.48 ± 0.10 (Tshaj tawm)
xim Dawb
PH 5 (H2O, 20 degree) (aqueous suspension)
Dej Solubility < 0.1 g/L (20 ºC)
rhiab heev Huab cua Sensitive
BRN 1782580
Kev ruaj ntseg: ruaj khov. Incompatible nrog muaj zog oxidizing tus neeg sawv cev, txo cov neeg ua haujlwm. Hluav taws kub.
InChIKey CXMXRPHRNRROMY-UHFFFAOYSA-N
LogP 3.2 ntawm 25 degree
CAS DataBase Reference 693-23-2(CAS DataBase Reference)
NIST Chemistry Reference Dodecanedioic acid (693-23-2)
EPA Tshuaj Registry System Dodecanedioic acid (693-23-2)
 
Cov ntaub ntawv kev nyab xeeb
Hazard Codes Xis
Risk Statements 36/37/38-36
Cov lus hais txog kev nyab xeeb 26-36-24/25
WGK Germany -
TSCA Yog lawm
HS Code 29171990
Cov Ntaub Ntawv Muaj Xwm Ceev 693-23-2( Cov ntaub ntawv muaj phom sij)
 
MSDS Cov Ntaub Ntawv
Tus kws kho mob Lus
Dodecanedioic acid Lus Askiv
ACROS Lus Askiv
SigmaAldrich Lus Askiv
ALFA Lus Askiv
 
Dodecanedioic acid Siv Thiab Synthesis
Kev piav qhia Cov kua qaub no yog siv rau hauv kev tsim cov nylon (nylon - 6,12), polyamides, coatings, adhesives, greases, polyesters, dyestuffs, detergents, nplaim retardants, thiab fragrances. Nws yog tam sim no tsim los ntawm fermentation ntawm ntev-chain alkanes nrog ib tug tshwj xeeb hom ntawm Candida tropicalis. Nws cov monounsaturated analogue (traumatic acid) tau piav qhia hauv qab no.
Chemical Properties dawb crystalline hmoov
Siv Induced mutation ntawm dodecanedioic acid tsim Candida tropicalis.
Siv Dodecanedioic acid yog siv los ua ib qho nruab nrab rau plasticizers, lubricants thiab adhesives. Nws kuj yog siv rau hauv cov tshuaj tua kab mob, cov txheej txheem qib siab, cov ntaub ntawv pleev xim, corrosion inhibitor thiab surfactant. Nws pom daim ntawv thov hauv engineering yas xws li nylon 612.
Kev npaj Dodecanedioic acid yog npaj los ntawm cyc1ododecene (tau los ntawm butadiene) los ntawm txoj kev uas zoo nkaus li zoo rau cov siv los npaj adipic acid los ntawm benzene. Cyclododecene txo mus rau cyclododecane, uas yog oxidized ua ntej mus rau ib tug sib tov ntawm cyc1ododecanol thiab cyclododecanone thiab ces mus rau dodecanedioic acid. Dodecanedioic acid yog cov xim tsis muaj kob crystalline, mp129 degree.
Txhais ChEBI: Ib qho alpha, omega-dicarboxylic acid uas yog dodecane uas cov methyl pawg tau oxidised rau cov carboxylic acids sib xws.
Txoj Kev Purification Crystallize dioic acid los ntawm dej, 75% lossis 95% EtOH (solubility yog 10%), lossis glacial acetic acid. [Beilstein 2 IV 2126.]
 
Dodecanedioic acid Kev npaj cov khoom thiab cov ntaub ntawv raw
Cov khoom siv raw Hydrogen peroxide-->1,3-Butadiene-->1-Dodecanol-->CYCLODODECANE-->Cyclododeca-1,5,9-triene
Cov khoom npaj 14-METHYLPENTADECANOIC ACID-->CYCLOTETRADECANE-->Dodecanedioic acid, Mono(1,1-diMethylethyl) ester-->1,12-Dodecanedioyl dihydrazide-->Dodecanedioic acid, 1-(phenylmethyl) ester-->OXACYCLOTRIDECAN-2-IB

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